Phase 2 (Šmartno at Pohorje)

Technical analysis

Pigments: white lime, yellow ochre, red earth, cinnabar, carbon black, lead pigment(s)

Analytical techniques: OM, SEM-EDX, FTIR

The plaster is hard, with a considerable content of lime and less aggregate. The aggregate grains are both angular and rounded, with many translucent grains, while some multicolour particles (red, brown) are also visible (Fig. 1). The plaster, at least on the ribs (Fig. 2) but probably also on the vault, seems to be thinner and contains less aggregate, which makes it lighter and more durable. In most of the samples, at least one layer and sometimes two or even more layers of limewash have been detected, which often also resemble thick, slightly tinted colour layers (Fig. 3). XRD analyses of the plaster have not yet been carried out, but it seems that the same type of plaster appears on both the ribs and the walls. The borders between the giornate are not visible, which is to be expected given the early date of the mural’s creation.

The selected pigments are of earth origin – earths and minerals – as revealed by the SEM-EDX and FTIR laboratory analyses. The white colour is white lime, also used as limewash; the abovementioned analyses have revealed a high calcite content. The yellow colour is yellow ochre, predominantly containing aluminium and silicon, i.e. mostly alumosilicates. The red colour is mostly red earth (Fig. 2), as identified by the SEM-EDX analytical techniques based on iron. However, the content of this element is surprisingly low and only revealed by mapping (the analysis of the surface of the sample at several consecutive points) and not by point analysis. Cinnabar was probably used for certain bright red details (e.g. the mouth). This pigment has also been detected in some of the red particles in the blue colour from the background, for example near the neck of Christ Pantocrator (Fig. 4). However, further investigation is required, as it is unlikely that this expensive pigment would have been used for the background. The blue on the background, which looks blackish already at first glance, is actually a mixture of some organic black (bone or carbon black, or perhaps a mixture of both because both phosphorus and carbon have been detected, while the electron microscope has even revealed a bit of charcoal), white lime, and red earth. The colour sample from the bluish background in the Cain and Abel scene on the triumphal arch suggests a potential secondary recrystallisation, which could have caused the brighter patches on the colour layer. The blue-grey background colour was applied on limewash (Fig. 4) and, in some places, directly on fresh plaster. The chemical analyses have not detected any azurite. The black pigment used in the thickly applied colour layers, used mainly for the final contours, is carbon black. For the green colour, the painter used two pigments: green earth as the cheaper alternative and malachite as the more expensive one. The analysis of the sample of the green drapery belonging to the saint portrayed on the southern wall to the left of the window has revealed two layers of green: a brighter base and a darker upper layer, which is a part of the garment modelling (Fig. 5). The upper layer is made of a mixture of green earth and a little bit of malachite (a modest presence of copper), while the lower layer is a mixture containing a lot of lime and very little malachite, as copper is barely visible next to calcium on the SEM-EDX spectrum. A few blackened parts, such as the book held by Christ Pantocrator or some of the clothing, suggest that some lead pigment might also have been used. The SEM-EDX analysis has also confirmed the presence of lead in one of the samples. The colours are applied in rather thick layers. The main binder is lime from the plaster and limewash, while the painter additionally bound the pigments with lime water or lime milk. He may have added some organic binder, at least for the finishing touches.

The basic elements were painted al fresco, while most of the mural was completed using the lime technique. The plaster, hard and rich in lime, had dried before the painting was finished, as it had to be applied on large surfaces. Thus, only the underdrawing and the basic colour tones were applied al fresco (Figs. 1–2), while the colour modelling and the additions were applied al secco or on limewash (Figs. 4–5), which increased the binding power of the drying plaster. The presence of extremely thin layers of limewash has been established by the cross-sections and the optical and electron microscope photographs. The painter applied limewash mainly under the colours of the draperies but also on some of the carnations, where he also used colour modelling with thick, slightly pinkish lime layers (Fig. 3). This increased the binding power of the lime, but still not enough for the colours to adhere firmly to the base. Nowadays, the colour layers are peeling off the plaster in thin laminae. In the spots with multiple layers, individual layers are also peeling off. After completing the underdrawing, underpaintings, and local tones, the artist probably modelled the faces and hands and then moved on to the draperies. He finished with the details such as the eyes, mouth, attributes, and final contours. These parts were mostly painted on an already dry plaster, so they are very poorly preserved.

In the past, the painting was hammered and covered with a new layer of plaster, leaving it severely damaged. The hammered parts were filled in during the most recent restoration works, and the painting was heavily retouched. The painting process and modelling had already been partly evaluated before the retouching. Some of the halos were incised in fresh plaster and decorated with ray-shaped pouncings, while on some of the figures, incisions were also used to accentuate the collars and sleeve edges of the garments. The figures depicted on the vaulting ribs do not reveal any incisions; perhaps they were not made because of the thin plaster. The painter also outlined the entire composition on the fresh plaster, using black for the underdrawing. This is best seen on the northern wall, on the arches of the architecture (which coincide with the remains of the coloured arch on the right side of the wall) and on the lower centre part of the same wall between the three preserved apostles, where the columns of the architectural niches were outlined with quick, imprecise strokes (Fig. 6). The final mural does not always precisely coincide with the underdrawing, which was apparently used only as a draft. In many places, the underdrawing is covered by limewash. In some of the figures, it appears that the painter also used a red underdrawing, which he then covered with a strong black final contour (Fig. 7). Basic colour tones were mostly used, and no underpaintings have been detected as colour layers below the upper colour layer. Many of the faces have been destroyed as the colour layer has fallen off. We can also see a rather schematic face modelling with a black contour used to paint the strong, slightly semi-circular eyebrows, extending from the root of the nose to the edge of the head. Underneath are large, wide-open eyes with large pupils. The noses are straight, though some of them appear slightly potato-shaped. In the frontally portrayed faces, only one side of the nasal ridge is outlined, while the other is indicated with a pink shadow descending from below the eye. Small mouths with pointed tips of the upper lips are heart-shaped. In several places, their vivid red colour has been preserved. For the colour modelling of the carnation, the painter applied the colours in several layers, mostly on top of the basic orange colour, as can still be clearly seen in the figure of St Nicholas (Fig. 3a). He applied several thick layers over the basic colour, which seem like limewash but vary slightly in tone. The first one or two layers are white, followed by one or two layers of a slightly denser light pink colour, ending with yellow and pink modelling. A cross-section of a sample from the face of the abovementioned saint also reveals a sequence of colour layers (Fig. 3b). There are no fine strokes indicating the use of a thin brush. The highlighted nasal line with a vivid red line and the pink-coloured area around the eyes represent a particular feature of this painter. He also used the same pink colour to outline the cheekbones, the outer edges of the three-quarter profiles and the wrinkles on the forehead, as well as to finish the forehead just below the hairline. The strokes are uniform and decisive. Finally, he probably painted the bright red dots to liven up the cheeks and used the same colour for the mouths, which, however, have mostly fallen off – except in the case of the angel next to Christ in the mandorla on the eastern wall. He also modelled the necks, either with horizontal, slightly curved pink strokes on a white base or with white diagonal V-shaped lines on a pink base. He applied the black contour as a finishing touch. The hands are narrow and feature long fingers. They are modelled in a similar manner and with the same colours as the faces. The shading is applied using pink colour along the undersides of the fingers, on the wrists, and on the palms of the hands. The painter applied the colours with a broad brush. He finished the outer lines with a strong black contour. The outer edges of the hair and beard are painted with a black contour, while the inner modelling is grey or yellow, the latter made with ochre. The addition of white creates light reflections. For the modelling of the draperies, the painter sometimes used the bright basic colour of the plaster itself and painted the lines of the folds on it with a broad brush (Cain), while sometimes he modelled the folds on the basic local colour of the drapery, in this cases with a darker tone. He often applied the colours on a thin limewash and used a broad brush to paint the folds in a darker colour over them (Fig. 5). The limewash is peeling off the plaster, which means that the painter created the draperies during the final works when the plaster was already too dry to bind the pigments. He applied the modelling with an intermediate tone between the base and the folds, but there are no soft transitions. The garment of the left thief in the Crucifixion scene was certainly painted al secco, as can be seen on the lower edge: the colour has faded considerably, while underneath, we can see the vertical part of the cross. The painter initially planned to end the cross higher up but then decided to cover it with the drapery. The books of the apostles were also painted al secco; their colour is peeling off the base. The painter modelled the architecture and the crosses in the same manner. He created the outer outline with a wide red band (the architecture) or an orange band (the crosses) while filling the interior with red, pink, or white colours or with the colour of the painting base – the limewash. This way, the painter attempted to create a three-dimensional effect for the crosses and architectural niches. It appears that the author of this mural did not use fine brushes. He applied the colours in broad lines that did not allow fine modelling. On the ribs of the vault as well as on the walls and vault itself, the modelling, the composition of the plaster, and the choice of pigments are identical. Thus, the mural in the chancel appears to be a single work.

Gallery

Virtual 360° view

Šmartno at Pohorje, Parish church of St Martin, Phase 2 (Šmartno at Pohorje), 2024 (last updated 19. 12. 2024). Corpus picturarum muralium medii aevi, https://corpuspicturarum.zrc-sazu.si/en/poslikava/phase-2-smartno-at-pohorje/ (9. 9. 2026).

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