Triumphal arch
Pigments: white lime (calcite), yellow earth (goethite), red earth (haematite), lead pigment (?)
Analytical techniques: OM, Raman, XRD
Interior triumphal arch wall, chancel
Pigments: white lime (calcite), yellow earth (goethite), red earth (haematite), green earth or malachite (?), azurite (?), carbon black
Analytical techniques: OM, Raman, XRD
Triumphal arch
The church features several layers of murals, but not all of them are clear because of damage and fading. Three layers are distinguishable in certain parts of the southern side of the triumphal arch, which is best seen in the area where the central figure is painted. In this middle zone, one sample was taken from each of the three layers, while a single sample was collected from the lower figure to determine which layer it belonged to. We also took a sample from the lower (or possibly middle) layer on the northern side of the arch in an attempt to identify these layers more properly. During the sampling process, the strength of the plaster varied between the three layers already by feel. The oldest layer (sample VMD 7) consists of the most brittle plaster, which is also rather thin and uneven as if it traced the stone wall beneath. The middle layer of plaster, which had also been heavily hammered before the new mural was painted, is also exceedingly fragile (VMD 8). The cross-sections of the samples confirm that all the plasters consist of lime and sand of different granulation and grain colours. Similarities can be detected between the plaster on the northern wall (VMD 2, Fig. 1), the one beneath the lower figure on the southern wall (VMD 1, Fig. 2), and the one belonging to the middle layer of the middle band (VMD 8, Fig. 3). All three plasters show an orange hue, while the sand consists of dark, orange, and translucent grains. X-ray diffraction (XRD) analysis reveals that the plaster is composed of a generous amount of aggregate (quartz) and only a little binder (calcite), which is why the plaster is so crumbly. At the same time, it also contains some feldspars and muscovite, i.e. impurities that also affect the quality of the plaster. The plots of both layers are very similar, which may indicate that they were painted by the same workshop within a short period of time. The top plaster (VMD 9), on which the blackened figure was painted, is between three and five millimetres thick and the most solid, perhaps consolidated. The cross-section of the sample (Fig. 4a–4b) reveals a somewhat orange plaster with orange aggregate grains, similar to the plaster on the earlier two layers (VMD 7, 8). However, its chemical composition is different: while it is also high in quartz and even lower in calcite, i.e. binder, it also contains a significant amount of impurities such as feldspars and muscovite, indicating a poorly washed sand and an inferior-quality plaster. In terms of its composition, it is similar to the plaster beneath the kneeling figure on the inside of the triumphal arch (VMD 4a) – perhaps this is the same layer of the murals. On the lower layer of the same side, i.e. the southern end of the triumphal arch, the plaster is also solid, while it is exceedingly brittle on the opposite, northern side of the triumphal arch (VMD 2). Thus, we can conclude that the latter must have been applied simultaneously as the first or second painting layer on the southern side (VMD 7, 8), while the former coincides with the third layer. In all cases, the sand was most likely locally sourced and used in murals from different periods. On the northern side of the inner triumphal arch, we can still see the giornate applied individually for each figure.
Interior triumphal arch wall, chancel
We can discern two layers of paintings on the triumphal arch wall, as the kneeling (donor?) figure was painted on the upper layer of plaster. It may have been added later, but belongs to the same set of murals. On the chancel walls, the fragmentary nature of the murals makes it unclear whether there are two or even more layers and how they follow each other, except in the window splay, where the diamond-shaped decoration was painted over the figure of a female saint. Samples were only taken from the interior triumphal arch wall, as the paintings on the chancel walling and ceiling are too high. Already with the naked eye, we can see that all of the plaster consists of lime and sand, just like in the case of the triumphal arch. The X-ray diffraction (XRD) analysis of a sample taken from the chin of the kneeling figure in the corner of the northern part of the interior triumphal arch wall (VMD 4a, Fig. 8) confirms that it is composed of lime and sand (mainly quartz). However, the aggregate content is considerable, contributing to the plaster’s brittleness. The presence of feldspars and muscovite indicates poorly washed sand, which also affects the quality and durability of the plaster. The X-ray diffraction XRD analysis of this plaster reveals a plot that is almost identical to the plaster from the most recent, uppermost layer on the triumphal arch (VMD 9), which is also confirmed by the cross-sections (Fig. 4a). The results of the analyses of the plasters therefore indicate that the mural was painted at the same time. On the other hand, the three samples taken from the lower bordure of the Nativity scene (Fig. 9) and the drapery of the angel in the Annunciation scene (Fig. 10) differ from this one and all those taken from the triumphal arch: the aggregate contains elongated greyish grains, which are absent from all the other plasters at this location. Moreover, a thin layer of plaster or limewash can also be detected between the plaster and the paint layer. Although we also found limewash on the lower (or middle) layer of the northern side of the triumphal arch (Fig. 1), it appears white on the sample, whereas it is translucent on the samples taken in the chancel, indicating that this is not the same register. Obviously, the plaster had already been dry before this thin layer was applied, as the already-formed lime crust is clearly visible on the surface. The analysis of the samples also reveals a lime and sand plaster mainly consisting of aggregate (quartz) and much less lime. At the same time, the feldspar and muscovite content is much lower here than in the case of the samples from the kneeling figure (VMD 4a) or the figure painted on the upper layer of the triumphal arch (VMD 9). The XRD analysis plots are similar to those for the lower two layers from the triumphal arch (VMD 7, 8). However, the cross-section of the sample from the interior triumphal arch wall (VMD 3, Fig. 9) reveals a different plaster than that of the layers from the triumphal arch itself (Figs. 3, 5). Judging from the plasters, the mural on the upper part of the interior triumphal arch was therefore painted by another painter than the image of a kneeling figure or the paintings on all three layers of the triumphal arch. Nevertheless, the blackened pigments present on this mural and the upper layer of the arch suggest the possibility that the murals were at least painted by the same workshop. It is also possible to distinguish the giornate in some places.
Triumphal arch
From the oldest layer, we only have a sample of the red colour, whose granulation and pigment colour suggest red earth (Fig. 5). However, white lime was also used, as can be seen in the conserved fragment. In the middle layer (the lower figure on blue background), the white, yellow, red, and blue colours are still preserved . As Raman spectroscopy indicates, the pigments used here were white lime (calcite), yellow earth (goethite) and red earth (haematite) (Figs. 1, 3), while the blue (azurite?) has fallen off the sample and we can either only see a thin grey underpainting (veneda) (Fig. 2) or the colour was originally just grey, conveying the optical appearance of blue. On the upper, most recent layer, the dark draperies and especially dark carnations attract attention. Although they indicate the use of lead pigments, which have darkened due to atmospheric effects, this was not confirmed by Raman spectroscopy, but FTIR analysis of the corresponding sample (VMD 9) reveals a presence of lead white (Fig. 4a). The primary binder is definitely lime from the plaster. However, at least on the top layer, where we suspect the use of lead pigments, the pigments must also have been impregnated with some sort of organic binder to paint certain surfaces and complete the final dry modelling.
Interior triumphal arch wall, chancel
White lime (calcite), yellow earth (goethite), red earth (haematite), green earth or malachite (no samples taken), and probably azurite were used on what is presumably the lower layer. The darkened areas indicate chemical changes that the pigments have undergone due to atmospheric influences. A few black stains have formed on the blue background, which could indicate a chemical alteration of the azurite, thus confirming its use. Mary’s mantle also still shows an intense turquoise colour in some places, though it has turned black in others. In most cases, darkened colours most likely contain lead pigments, lead white, yellow massicot or red minium, though no lead pigments were confirmed by Raman nor FTIR analyses; only silicates and iron oxides were found. The use of lead yellow is indicated, for example, by the blackened areas on some of the halos, as this pigment would often be used instead of gold because of its intense bright colour (Figs. 11–12). The cross-sections taken from the darkened parts also confirm the change in pigment, as can be seen clearly in the sample of the angel’s drapery (Fig. 10). There is a thick brown colour layer on the thin layer of limewash/plaster, which is definitely not the colour used to paint the angel’s cloak or hair. The density and compactness of the colour layer also indicate that the pigment was impregnated with a sort of organic binder. The primary binder in most paintings is definitely lime from the plaster (and from the presumable limewash). On the supposed upper layer, to which the kneeling figure in the corner (the donor?) also belongs, we can see the use of white lime, yellow earth, and red earth. Unfortunately, the colour layer is not visible in the cross-section of the carnation sample (Fig. 8); it has probably peeled off. The primary binder is lime from the plaster, though organic binders were probably also used for the final details.
Triumphal arch
At least the base of the oldest layer was painted al fresco, as confirmed by the cross-section of the sample (Fig. 5) and the good preservation of the colour layer on the wall. The middle layer was also painted mainly on fresh plaster (Fig. 3). For some elements, such as the borders, the lime technique was also used, which can be inferred from the sample from the northern side of the triumphal arch (Fig. 1). The final details must have been painted using the al secco technique, although this cannot be confirmed by the samples taken. However, the modelling has peeled from the mural, which supports this hypothesis. Also for the most recent layer, al fresco painting was chosen as the basic painting technique, though it was undoubtedly combined with al secco painting (Fig. 4).
Interior triumphal arch wall, chancel
Given the relatively good preservation of some of the painted surfaces on both layers, the murals were mostly applied to fresh plaster. The samples from the Annunciation and Nativity scenes also indicate the use of limewash or perhaps a very thin new fresh plaster layer. They were taken from the less important painting locations, which were thus probably completed at the very end, such as the bordures (Fig. 9), draperies, and backgrounds (Fig. 10). The results of the analyses will reveal whether this was a lime technique used for these secondary areas when the plaster was already too dry for the pigments to bond properly. The dry technique was probably used more extensively for the presumably older layers. This can be inferred from the blackened areas, most probably painted with pigments that required dry application (lead, azurite). Also for the top layer (the kneeling figure), at least the final details had to be painted al secco, but they have fallen off.
Triumphal arch
The oldest layer is too poorly preserved to speak of any modelling. The red line of the fragment was drawn in a decisive stroke with a broad brush. We attempted to evaluate the middle layer based on the lower saintly figure on the southern side of the arch and a few fragments on the northern wall, but it is not always clear to which layer the painted parts belong. There are no incisions, and red colour was used for the underdrawing. The saint’s head on the southern side is elongated, the facial features have not been preserved, and the hair is modelled with simple red lines defining the strands on an ochre base. The top layer is the most preserved, although it is also heavily damaged, in addition to significant colour changes. Again, no incisions are visible, while the underdrawing was probably painted in dark red colour, as it appears in some areas of the central figure on the northern side of the arch (Fig. 6). Perhaps the underdrawing also shows in the case of the facial features, and the final contour has actually fallen away. The figures feature slightly elongated faces, high-set semicircular eyebrows, large eyes with an accentuated upper eyelid (a thicker line) and large irises, from which the final colour has probably peeled. The nose protrudes from the inner eyebrow and appears straight. The lips are fleshy and feature prominent shading under the lower lip. This may also be caused by the darkening of the colours, though it looks like the two central figures on either side of the triumphal arch, whose faces are the best preserved, were not painted by the same hand. The face of the figure on the southern wall conveys the impression of slightly more semicircular eyebrows, smaller eyes, a narrower, straight nose and wider lips, while the one on the northern wall is “softer” and closely resembles the donor (?) figure on the inner side of the triumphal arch (Fig. 7). Both figures have high eyebrows that rise slightly above the iris and identically shaped almond-like eyes with large irises and a broad upper eyelid ending in a thicker contour. The noses and mouths cannot be compared precisely, although similarities can be inferred. In all likelihood, this is the same painting layer.
Interior triumphal arch wall, chancel
Only fragments of the painting have been preserved. In some places, it appears as if we are looking at two layers. The cross-sections of the samples confirm this assumption, especially judging from the plaster and the presence or absence of limewash/thin plaster. On the other hand, the painting process suggests a single layer instead – only the kneeling (donor?) figure can be more reliably identified as a subsequent addition. The image of a certain Holy Bishop behind the altar may also be from another time. Especially the red underdrawing, which is visible in many places as the paint layers have peeled off, indicates that the parts belong to the same mural. Regardless of the specific differences in the modelling of the faces, a dark red colour, using the same thick brush and decisive strokes, was used for the entire underdrawing. The almost complete absence of any corrections suggests good preparation and a skilled master. It would be difficult to find such a similarly executed underdrawing on two separate layers of murals painted at different times. The differences in the modelling of the faces may suggest that two masters divided the work. On the one hand, the figures with large eyes and huge irises, the accentuated lower edge of the upper semicircular eyelid, and the even more prominently curved eyebrows above the eyes, , stand out. The nose is rather potato-shaped and features prominent nostrils, while the lips are fleshy and separated by a line in the middle (Figs 7, 11–12). Such faces belong to the donor (?), the nursing Virgin Mary, the female saint in the walling, and the saintly figure on the northern side of the triumphal arch (Fig. 6). On the other hand, the figures in the Annunciation, Nativity, and the Kiss of Judas/Arrest of Jesus scenes, as well as the assisting figures in the Maria lactans scene (Fig. 11), have smaller, narrower eyes; their eyebrows are often simply semicircular without a rise in the middle; and all of their noses are potato-shaped and in some cases painted better than in others. Most of the heads in all scenes are slightly elongated and feature slightly emphasised inner cheekbones when painted in a three-quarter profile. However, there are also a few round and stocky heads. The hands are somewhat clumsy but with long fingers in various positions, rounded at the tips. The painter painted the basic colour layers for the carnations, draperies, and backgrounds locally using a broad brush, and no underpaintings can be discerned. Perhaps the azurite (blue backgrounds, Mary’s mantle) was applied to a grey or red colour base. The colour modelling, if any ever existed, has not been preserved. Thin incisions were used for the double circles on the saints’ halos (only Jesus has a single incision) and probably also for the linear bordures outlining the bands. It seems that the kneeling figure (donor?) was added subsequently. Perhaps it is just the relevant giornata that stands out in such a manner, or maybe the figure was actually added later, but the same artist was hired for the job. On the opposite side of the triumphal arch wall, we can see the remains of a beardless figure, which probably had its counterweight on the opposite side, i.e. below the kneeling (donor?) figure.
Everything suggests that the upper layer of the mural on the triumphal arch and the mural in the chancel (except for the donor figure) were painted simultaneously. We have yet to establish why the faces of the two central saintly figures on the triumphal arch have also blackened while the others have not. Given that there are two older murals under the most recent layer on the arch, it is likely that at least one of these two extends somewhere else, either into the chancel and/or the nave. For a definitive interpretation, we would require more samples from more locations.
Vuzenica, Succursal church of the Virgin Mary on Kamen, Stage 1 (Vuzenica, church of the Virgin Mary on Kamen), 2024 (last updated 29. 8. 2024). Corpus picturarum muralium medii aevi, https://corpuspicturarum.zrc-sazu.si/en/poslikava/phase-1-church-of-the-virgin-mary-on-kamen-vuzenica/ (11. 9. 2026).
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